Na 12-OH Soap · Fibrous Structure · Drop 175 °C · Water-Emulsifying

Sodium Soap Grease Manufacturing India —
Legacy NLGI 2 BOM & SOP

Sodium soap grease is legacy fibrous-structure grease using Na 12-hydroxystearate as thickener. Distinguished by stringy / thread-like texture, drop 175-185 °C, and unique water-EMULSIFYING property (opposite of lithium's water-resistance). Historically dominant in water pump bearings; now niche legacy + select water-emulsion applications. India market ~500-1,500 MT/year (declining vs lithium). This guide gives the BOM and the critical controlled-cooling process discipline.

Na 12-OH
Fibrous Soap
175-185 °C
Dropping Point
Water-Emul
Opposite of Li / CaSX
₹95-145
Ex-Works ₹/kg
Recommended Formulation — The BOM

Working Sodium Soap Grease
NLGI 2 Legacy BOM

LC-GR-NA-NLGI2 — Recommended Recipe
Final · NLGI 2 Sodium 12-Hydroxystearate Legacy Grease · Water-Emulsifying
ComponentFunction% (m/m)Indian Supplier
Group I SN500 base oilCarrier base oil76.0%IOCL / HPCL Group I
12-Hydroxystearic acid (or stearic acid)Soap-forming fatty acid9.0%Croda / Godrej / Wilmar India
Sodium hydroxide (NaOH)Alkali for saponification1.5%Indian inorganic suppliers
Mixed ZDDP AW (low treat)Anti-wear0.8%Lubrizol / Lubechem LC-AW-ZDDP
2,6-DTBP phenolic AOOxidation inhibitor0.4%BASF Irganox
Alkenyl-succinic-acid CIFerrous rust inhibitor0.4%King K-Corr 200
PIB tackifier (Mn 1300)Adhesion0.5%BASF Glissopal
Mineral oil flash-offMixing carrier — partially flashes5.0%IOCL Group I 150N
Yellow / amber dyeTraditional Na grease colour100 ppmClariant pigments
Group I 150N diluentConsistency fine-tune6.4%IOCL Group I
TOTAL100.0%

Process: saponify fatty acid + NaOH slurry (NaOH in 5-8% warm water) in base oil at 195-215 °C; CRITICAL — controlled slow cool at 1-2 °C/min through 90-120 °C window for fibrous crystal habit (fast cool destroys structure); add additives below 100 °C; GENTLE single-pass mill (high-shear mill breaks fibres). QC: drop 175-185 °C, penetration 265-295, working stability NLGI 2 → 3-4 after working (less stable than lithium). Ex-works ₹95-145 / kg at 5 MT batch — competitive with EP2 lithium for cost-sensitive niche customers. The AW and rust chemistry draws on our grease additive package range; batch QC follows our ASTM lubricant & grease testing protocols, and the slow-cool kettle is costed in our grease plant setup cost guide.

Questions & Answers

Frequently Asked About
Sodium Soap Grease

What is sodium soap grease?

Sodium soap grease is legacy grease using sodium 12-hydroxystearate as thickener. Distinguished by fibrous structure (long needle-like soap fibres giving 'stringy' or 'thread-like' grease texture), drop point 175-185 °C, and unique water-EMULSIFYING property — Na soap grease emulsifies water rather than rejecting it.

Used historically in water pump bearings, older industrial ball bearings, low-temperature transmission grease. Largely replaced by lithium grease since 1950s due to lithium's superior water-resistance + dropping point. Still in service for select legacy applications and as low-cost industrial grease in some markets. For higher-temperature replacements, see our lithium complex grease manufacturing and polyurea grease manufacturing routes.

Sodium soap grease BOM?

Sodium soap grease NLGI 2 BOM (%): Group I SN500 76%, 12-HSA (or stearic acid) 9%, NaOH 1.5%, ZDDP 0.8%, phenolic AO 0.4%, ASA CI 0.4%, PIB tackifier 0.5%, mineral oil flash-off 5%, yellow/amber dye 100 ppm, balance Group I diluent.

Process: saponify at 195-215 °C; controlled slow cool at 1-2 °C/min for fibrous crystal habit; add additives below 100 °C; gentle single-pass mill. Drop 175-185 °C, penetration 265-295.

Why sodium grease emulsifies water?

Sodium 12-hydroxystearate soap is hydrophilic — the sodium ion has high affinity for water. When water contacts Na grease, the soap partially dissolves and forms water-in-oil emulsion that retains lubricant film. OPPOSITE of lithium (Li 12-OH) soap which is hydrophobic and rejects water.

Historically valued in water pump bearings — small water leakage absorbed into grease without immediate lubrication loss. Modern water pumps use sealed-for-life lithium complex or polyurea — sodium grease application now niche / legacy only.

Where is sodium grease still used?

(1) Legacy industrial maintenance — older ball bearings with established Na grease spec. (2) Some marine boat hull bearings + propeller stuffing box — water emulsifying preferred. (3) Some textile spinning frame bearings — vintage equipment. (4) Very-low-temperature applications below -20 °C where lithium becomes too stiff.

Indian total Na grease volume small ~500-1,500 MT/year (declining) vs lithium grease ~50,000+ MT/year. Niche supplier opportunity rather than mainstream. Producers serving these niches usually also run non-soap lines such as bentonite clay grease manufacturing and high-temperature barium complex grease manufacturing to broaden their catalogue.

India sodium grease brands?

Indian Na soap grease suppliers (small volume): IOCL Servo Sodium Grease, BPCL Mak Sodium Grease, HPCL Sodium Grease — legacy SKUs. Most large blenders deprioritised Na over 2000-2020 as lithium volume grew. Small Indian private-label aftermarket suppliers still produce Na grease for textile, vintage industrial.

Pricing ₹120-200 / kg retail (cheaper than EP2 lithium ₹150-250 / kg). Lubechem custom (LC-GR-NA-NLGI2) ex-works ₹95-145 / kg at 5 MT batch. Many of these blenders also diversify into adjacent chemistry such as DEF / AdBlue manufacturing to use spare plant capacity.

Process challenge — fibrous structure?

The technical hurdle in Na grease is producing the characteristic fibrous soap structure. Critical process parameter is COOLING RATE after saponification — 1-2 °C/min controlled cool required. Fast cool (>5 °C/min) destroys fibrous structure, giving granular soap with poor body. Slow cool (<0.5 °C/min) gives over-fibrous grease that's too stringy.

Milling must be gentle — high-shear mill breaks fibres. Indian Na grease producers use jacketed slow-cool kettle + single-pass roller mill instead of high-shear colloid mill used for lithium. Process discipline distinguishes good vs poor Na grease.

Related Services

From Sodium Brief
to Legacy Grease

Need Sodium Soap
Grease Built?

Share your legacy application + spec match requirement and volume. We respond within one business day with the BOM and ex-works cost.