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OCP · PMA · PIB · Star Polymer · SSI 20-50 · Multigrade

Viscosity Index Improver India —
OCP, PMA, PIB, Star Polymer Selection

Viscosity index improvers (VII / VM = viscosity modifier) are the polymer additives that make multigrade oil possible — they thicken oil at high temperature without thickening it as much at low temperature, giving the SAE 5W-30, 15W-40 multigrade characteristic. OCP (olefin copolymer) is the workhorse; PMA (polymethacrylate) is the multifunctional premium chemistry; PIB (polyisobutylene) is for gear oil; star polymer is racing-grade specialty. This guide covers chemistry families, shear stability index (SSI), treat rate by service and Indian sourcing.

4–10%
Treat in Finished Oil
OCP/PMA/PIB
3 Major Chemistries
SSI 20–50
Stable Range
60–100 VI
VI Lift Range
VII Chemistry Families

Six VII Chemistries
Used in Lubricant Blending

OCP SOLID
Ethylene-Propylene Copolymer
Solid OCP — pellet or crumb form, dissolved by the blender in 100N base oil at 65-75 °C. SSI 25-50 grades available. Workhorse VII for PCMO and HDD multigrade. Lowest cost per VI lift. Lubrizol Viscobase 9, Afton HiTEC 5777, Infineum V387, Mitsui Lucant.
PCMO & HDD
OCP LIQUID
Pre-Dissolved Concentrate
OCP pre-dissolved at 10-15% active in 100N base oil. Easier handling for blenders without VII dissolving capability. Slightly higher landed cost per kg active polymer but saves blender labour and reduces blending time by 1-2 hours per batch.
Easy Blend
PMA
Polymethacrylate Multifunctional
Copolymer of C10-C18 alkyl methacrylates. Multifunctional — provides VII + built-in PPD function (no separate PMA-PPD needed). Better low-temp viscometrics (lower CCS / MRV) than OCP at equivalent VI lift. Premium PCMO ILSAC GF-6 / GF-7 standard. Evonik Viscoplex 5151, Lubrizol Sandura.
GF-6 / GF-7
PIB
Polyisobutylene
Polyisobutylene Mn 1300-2300. Used as VII in gear oil (GL-4, GL-5), some hydraulic, and industrial circulating oil. Not used in multigrade engine oil because of poor SSI (shears down quickly under engine shear). Mostly displaced by OCP in modern formulations.
Gear Oil
STAR POLYMER
Hydrogenated Styrene-Isoprene
Star architecture — multiple polymer arms emerging from a central core. Hydrogenated styrene-isoprene block copolymer. Very low SSI (15-25), highest viscosity-thickening efficiency. Used in racing oil, premium GF-6 0W-20, and high-shear hydraulic. 3-4x cost of OCP. Lubrizol Viscobase HSD hybrid star-OCP.
Racing / Premium
DD-PMA HYBRID
Dispersant-Modified PMA
PMA copolymerised with dispersant-functional comonomer (N-vinylpyrrolidone, dimethylaminoethyl methacrylate). Combines VII with dispersancy — reduces separate succinimide treat. Used in HDD CK-4 and CI-4+ extended-drain. Evonik Viscoplex 10-series, Lubrizol Viscobase DD, Afton HiTEC 3419.
HDD Extended Drain
How VII Works

Coil Expansion Mechanism
Across Temperature Range

1
Low-Temperature Coil Contraction
At low temperature (sub-zero / cold-start), the VII polymer coil is contracted — minimal volume occupied, minimal viscosity contribution. Base oil viscosity dominates the cold-temperature behaviour. CCS at -25 / -30 / -35 °C measures this regime.
2
High-Temperature Coil Expansion
At high temperature (operating, 100-150 °C) the VII polymer coil expands — occupies more volume, thickens the oil. The expansion is reversible. This is why multigrade oil retains 5W cold-pour but reaches SAE 30 / 40 hot viscosity at 100 °C.
3
Shear-Induced Coil Alignment
Under high shear (engine bearing, gear mesh, hydraulic pump) the polymer coil temporarily aligns with the flow, reducing its effective thickening — called HTHS (high-temperature high-shear) viscosity loss. Reversible when shear stops. Measured by ASTM D4683 HTHS at 150 °C, 10^6 s^-1.
4
Permanent Chain Scission
At very high shear or repeated shear cycles, polymer chain physically breaks — permanent MW loss. Lower MW means lower viscosity contribution forever after. Measured by ASTM D6278 Bosch injector shear or KRL tapered roller bearing. SSI 25-35 retention is the PCMO target.
SSI vs Treat Rate

Shear Stability vs
Viscosity Lift Trade-Off

VII TypeSSI RangeTreat % (finished)VI LiftBest Service
OCP solid SSI-2522-286-9%80-95PCMO 5W-30 / 5W-40 API SP
OCP solid SSI-3530-387-10%80-100HDD 15W-40 / 10W-30 CK-4
OCP solid SSI-4540-489-12%75-95HDD 20W-50, lower-tier multigrade
PMA SSI-2018-253-6%60-85GF-6 0W-20 / 5W-30 premium
Star polymer SSI-1815-222-4%55-80Racing, premium 0W-20
DD-PMA hybrid25-324-7%70-90HDD CK-4 / CI-4+ extended drain
Service-Grade Selection

VII Treat for Common
Multigrade SAE J300 Grades

SAE GradeBase OilVII TypeTreat % (finished)
SAE 0W-20Group III 4cSt + PAO 4cStPMA SSI-20 or star2.5-4.5%
SAE 5W-30Group II 110N + Group III 4cStOCP SSI-25 or PMA SSI-225-8%
SAE 5W-40Group II 110N + 220NOCP SSI-308-11%
SAE 10W-30Group I SN150 + SN500OCP SSI-306-8%
SAE 10W-40Group I SN150 + SN500OCP SSI-308-11%
SAE 15W-40 HDDGroup I SN150 + SN500OCP SSI-357-10%
SAE 75W-90 Gear GL-5Group II 220N + 600N + brightPIB Mn 1300-23008-14%
ATF Dexron VIGroup III 4cStPMA SSI-157-10%
Suppliers

Six VII Suppliers
Active in India

LUBRIZOL VISCOBASE
OCP & Star Polymer
Viscobase 11 high-SSI low-treat, Viscobase 9 low-SSI shear-stable, Viscobase HSD hybrid star-OCP. India Mumbai. ₹240-340 / kg solid OCP; ₹650-900 / kg star. MOQ 5 MT.
Branded OCP / Star
AFTON HiTEC 5777
OCP & PMA
HiTEC 5777 OCP solid, HiTEC 3419 DD-PMA hybrid, HiTEC 5772 PPD. India Navi Mumbai. ₹230-330 / kg OCP; ₹420-560 / kg PMA.
Branded
INFINEUM V-SERIES
OCP for ILSAC GF-6
V387 OCP solid mid-SSI, V501 low-SSI HDD, V8211 PMA dispersant copolymer. India Mumbai. ₹240-340 / kg.
Branded GF-6
EVONIK VISCOPLEX
PMA Leader
Evonik (formerly RohMax) is the global PMA technology leader. Viscoplex 5151 PMA VII, Viscoplex 1-series PPD, Viscoplex 10-series DD-PMA. Premium GF-6 / GF-7 standard. India Mumbai. ₹420-580 / kg PMA.
Branded PMA
MITSUI LUCANT
OCP — Asian Volume
Mitsui Chemicals Lucant solid OCP. Strong Asia-Pacific aftermarket OCP. India via Singapore. ₹230-330 / kg.
Asian OCP
LUBECHEM CUSTOM
India Custom OCP
Lubechem custom OCP equivalent (LC-VII-OCP-LS low SSI, LC-VII-OCP-MS mid SSI, LC-VII-PMA premium PMA). ₹160-230 / kg OCP; ₹310-420 / kg PMA. MOQ 500 kg OCP, 200 kg PMA. 4-6 week lead.
Custom & IP-Transferred
OCP Manufacturing

Five-Step OCP
Polymerisation Process

1
Ziegler-Natta Polymerisation
Ethylene + propylene copolymerised with Ziegler-Natta catalyst (TiCl4 / AlEt3 system or metallocene) in hexane / toluene solvent at 30-60 °C. Comonomer ratio (ethylene:propylene 50:50 to 70:30) controls polymer crystallinity and oil solubility.
2
MW Control via Hydrogen
Molecular weight controlled by H2 chain-transfer agent dosing. Higher H2 = lower MW = higher SSI (shear-sensitive but lower viscosity contribution per kg). Target Mn 100,000-200,000 for shear-stable VII; 50,000-100,000 for high-SSI lower-cost VII.
3
Catalyst Quench & Wash
Catalyst quenched with alcohol; polymer solution washed with water to remove catalyst residues and Cl. Solvent recovered by stripping — polymer crumb / pellet is solvent-free product.
4
Pelletising or Dissolution
Solid OCP supplied as pellets / crumb / bales for blender dissolution. OCP liquid supplied as 10-15% active solution in 100N Group II base oil (pre-dissolved at the additive plant).
5
QC Release
QC: KV100 after dissolution in standard base, SSI by ASTM D6278 (Bosch injector), HTHS by D4683, viscosity-thickening efficiency (kg base oil thickened by 1 kg VII). Released for shipping.
Questions & Answers

Frequently Asked About
VII Polymers

PMA vs OCP — which is better?

Neither universally — they serve different roles. OCP (olefin copolymer, ethylene-propylene) is the lowest-cost VII per VI lift, workhorse for PCMO and HDD multigrade. Solid OCP gives high-SSI versions (shear stable) and liquid OCP gives low-SSI versions.

PMA (polymethacrylate copolymer) is 30-50% more expensive but multifunctional — built-in pour point depression (no separate PPD needed), better low-temp viscometrics, better fuel-economy retention (Mo-DTC + PMA synergy). PMA is the standard for ILSAC GF-6 / GF-7 premium PCMO. PIB is used in gear oil and some hydraulic, not multigrade engine oil. Star polymer (hydrogenated styrene-isoprene) is racing-grade specialty.

What is SSI and why does it matter?

SSI = Shear Stability Index, measured by ASTM D6278 (Bosch injector shear) or KRL tapered roller bearing shear. SSI is the % viscosity loss after a defined shear cycle — lower SSI = better shear stability = polymer chains hold up under shear.

PCMO API SP / GF-6 typically uses SSI 25-35 OCP. HDD CK-4 uses SSI 35-50 OCP. Hydraulic and racing oil use SSI 15-25 (very shear-stable). High SSI VII (>50) loses too much viscosity in service — KV100 drops below SAE J300 grade minimum after 100 hr engine operation.

How is treat rate decided?

Treat rate depends on base oil viscosity and target finished-oil viscosity. For SAE 5W-30 from Group II 110N base, VII treat is 6-8% OCP SSI-30. For SAE 5W-40 from same base, treat is 9-11%. For SAE 15W-40 from Group I SN150 + SN500 mix, treat is 4-6%.

PMA at half the treat rate of OCP gives equivalent VI lift but at 2-3x the cost — net cost slightly higher but lower MRV / CCS gives better cold-start. The blender calculates treat by KV100 target and VII KV100-thickening efficiency at SSI level.

What is permanent vs temporary VI loss?

Two failure modes. Temporary VI loss: at high shear (engine bearing, gear mesh, hydraulic pump) the polymer coil temporarily aligns with the flow direction, lowering its viscosity contribution — recovers when shear stops. Measured by HTHS (high-temperature high-shear viscosity, ASTM D4683).

Permanent VI loss: polymer chain physically breaks under high shear, reducing molecular weight permanently. Measured by KRL or D6278 SSI. Both matter — HTHS dictates fuel economy and engine protection at bearing; SSI dictates oil-change-interval viscosity retention.

Star polymer for racing — the claim?

Star polymer (hydrogenated styrene-isoprene block copolymer in star architecture) has higher viscosity-thickening efficiency per molecular weight than OCP, giving equivalent VI lift at lower treat rate. Plus very low SSI (15-25).

Drawback: cost is 3-4x OCP. Used in racing oil, premium PCMO ILSAC GF-6 0W-20, and high-shear hydraulic. Indian volume is small but premium-tier OEM aftermarket increasingly uses star polymer (or star-OCP hybrid like Lubrizol Viscobase HSD).

Indian VII availability and cost?

OCP solid (Lubrizol Viscobase 9, Afton HiTEC 5777, Infineum V387, Mitsui Lucant) lands at ₹240-340 / kg. OCP liquid concentrate at ₹180-260 / kg. PMA (Evonik Viscoplex 5151, Lubrizol Sandura) at ₹420-560 / kg. Star polymer at ₹650-950 / kg.

Lubechem custom OCP equivalent at ₹160-230 / kg (30-32% saving on branded). PIB Mn 950-2300 from BASF Glissopal, INEOS Indopol at ₹200-320 / kg.

Multifunctional PMA dispersant VII?

DD-PMA (dispersant-modified polymethacrylate) is PMA copolymerised with dispersant-functional comonomers (e.g. N-vinylpyrrolidone, dimethylaminoethyl methacrylate). Combines VII function with dispersancy contribution — reduces the need for separate succinimide dispersant.

Used in HDD CK-4 and CI-4+ for extended drain. Treat 4-7% in finished. Cost is 1.5-2x conventional OCP but saves on separate dispersant treat. Brands: Evonik Viscoplex 10-series, Lubrizol Viscobase DD, Afton HiTEC 3419.

Is custom VII economically viable?

For mid-volume blenders (>500 MT/year multigrade), custom OCP equivalent saves ₹20-40 lakh per year. The OCP route (ethylene-propylene Ziegler-Natta polymerisation, MW control by hydrogen, dissolution in 100N base oil) is well-established.

Indian blenders typically buy custom-blended VII rather than manufacturing in-house — Indian polymerisation reactor capacity for OCP is limited; PMA can be made at smaller scale. PMA custom is more accessible at small MOQ (200-500 kg). OCP custom usually requires 5 MT minimum batch.

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