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Quaternary Ammonium Organoclay · NLGI 2 · No Drop Point · 260+ °C

Bentonite Clay Grease Manufacturing —
Organoclay HT NLGI 2 BOM & Process

Bentonite organoclay grease uses quaternary ammonium-modified clay platelets as the thickener instead of metallic soap. Critical advantage: NO drop point — clay doesn't melt, grease structure persists to 260+ °C continuous. Used in steel mill ladle bearings, glass plant feeder, cement kiln support roller, ceramic furnace, very-high-temperature OEM. This guide gives the recommended BOM, polar activator chemistry, manufacturing process and Indian sourcing.

No Drop
Drop Point >300 °C
260 °C+
Continuous Service
Quat Amm
Modified Clay
8-12%
Clay in Finished
Recommended Formulation — The BOM

Working Bentonite HT Grease
Organoclay NLGI 2 BOM & %

LC-GR-BENT-HT — Recommended Recipe
Final · NLGI 2 Bentonite Organoclay HT Grease · Service 220-260 °C
ComponentFunction% (m/m)Indian Supplier
PAO 6 cSt base oilSynthetic base, thermal stable 260 °C70.0%INEOS Durasyn / ExxonMobil SpectraSyn
Organoclay (Bentone 27 / Cloisite / equiv)Thickener — quaternary-ammonium-modified bentonite9.0%Elementis Bentone / BYK Tixogel / Indian importers
Polar activator (propylene carbonate)Critical — exfoliates clay platelets3.0%BASF / Dow propylene carbonate
Sulphurised olefin EPExtreme pressure boost3.0%Lubrizol Anglamol / BRB
Mixed ZDDP AWAnti-wear1.5%Lubrizol / LC-AW-ZDDP
Methylene-bis-DTBP phenolic AOLow-volatility primary AO1.0%Albemarle Ethanox 4710
Alkylated DPA aminic AOHigh-temp secondary AO1.0%LANXESS Naugalube 438L
Ca sulfonate CIVapour-phase corrosion inhibitor1.0%LC-DTR-CASULF
Alkenyl-succinic acid (ASA)Ferrous rust inhibitor0.5%King K-Corr 200
MoDTC FMFriction modifier0.4%Vanderbilt Vanlube 829
Calcium nitriteVapour-phase rust0.5%Indian inorganic
PIB tackifier (Mn 1300)Adhesion0.5%BASF Glissopal
PAO 8 cSt diluentConsistency fine-tune8.6%INEOS Durasyn
Brown / amber dyeHT grease identification100 ppmClariant pigments
TOTAL100.0%

Process: pre-disperse organoclay in 70% PAO with high-shear at 60-80 °C; add propylene carbonate polar activator — CRITICAL STEP, clay exfoliates and gel forms here; cool to 50 °C and add EP / AW / AO / CI / FM / tackifier; mill 3-pass colloid mill to NLGI 2. QC: no drop point (>300 °C), penetration 270-285, 4-ball weld 315 kgf, D942 oxidation <5 kPa @ 100 hr. Ex-works cost ₹420-650 / kg at 5 MT batch.

Questions & Answers

Frequently Asked About
Bentonite Clay Grease

What is bentonite clay grease?

Bentonite organoclay grease uses thermally stable clay (sodium / calcium bentonite) modified with quaternary ammonium surfactant as the thickener — instead of a metallic soap. The organoclay forms a 3D structure in base oil that gives grease consistency.

Key advantage: NO drop point — clay doesn't melt, so the grease structure persists to 260+ °C continuous service. Used in steel mill ladle bearings, glass plant feeder bearings, ingot mould lubrication, cement kiln support roller, ceramic furnace, very-high-temperature OEM bearings.

Bentonite grease BOM?

NLGI 2 bentonite organoclay grease BOM (%): PAO 6 cSt 70%, organoclay 9%, polar activator (propylene carbonate) 3%, sulphurised olefin EP 3%, ZDDP 1.5%, methylene-bis-DTBP phenolic AO 1%, alkylated DPA aminic AO 1%, Ca sulfonate CI 1%, ASA 0.5%, MoDTC 0.4%, Ca nitrite 0.5%, PIB tackifier 0.5%, PAO 8 cSt diluent 8.6%, dye 100 ppm.

Process: pre-disperse organoclay in PAO with high-shear at 60-80 °C; add polar activator — clay exfoliates and gel forms; cool to 50 °C and add additives; mill to NLGI 2. No drop point, penetration 270-285, 4-ball weld 315 kgf.

What does the polar activator do?

Polar activator (propylene carbonate, methanol, water, ethylene glycol) is the critical chemistry step in bentonite grease manufacture. The quaternary ammonium-modified clay sheets are stacked when received as raw material. When dispersed in nonpolar base oil, the polar activator molecules penetrate between the clay sheets and force them apart (exfoliation).

The exfoliated clay platelets form a 3D network in the base oil that gives the grease its consistency. Without polar activator, the clay stays in unswollen aggregates and gives no thickening — the grease batch fails. Treat rate 2-5% polar activator.

Bentonite vs hectorite vs synthetic clay?

All three are layered silicate clays used as grease thickeners. Bentonite (sodium / calcium bentonite from natural deposits) is the cheapest and most-used. Hectorite (lithium-magnesium silicate) is a higher-purity natural clay with finer particle size — premium synthetic-grease feedstock. Synthetic hectorite (Laponite, Optigel) is engineered to high purity for cosmetic and pharmaceutical use, also used in premium grease.

For industrial grease application, bentonite is the workhorse — Bentone 27 / 38 (Elementis), Tixogel (BYK), Cloisite (BYK). Indian sourcing via importers.

Bentonite grease applications?

Steel mill ladle bearings at 260+ °C — Tata Steel, JSW, SAIL. Glass plant feeder bearings (Saint-Gobain, Asahi India Glass) at 200-220 °C. Cement kiln support roller at 200 °C continuous (Ambuja, UltraTech, Shree). Ceramic / sanitary kiln (HSIL, Hindware). Very high temperature OEM (continuous casting, foundry handling).

Brands: Kluber Petamo GHY 133 N (bentonite + ester), Mobil Polyrex Heavy Duty, Castrol Thermoshield Bentone, IOCL Servo Hytherm Clay. ₹520-1,200 / kg. Lubechem custom LC-GR-BENT-HT ex-works ₹420-650/kg.

Why no drop point?

Dropping point (ASTM D2265) is the temperature at which a grease's soap thickener melts and base oil separates. Bentonite clay doesn't melt at any temperature within the grease service range — the clay platelets are thermally stable to >300 °C (and decompose only at much higher temperatures).

The grease therefore has no measurable drop point; the temperature limit is dictated by base oil oxidation (synthetic PAO / ester ~260 °C) and additive thermal stability. This makes bentonite grease the natural choice for sustained service above 200 °C where soap-based thickeners (lithium complex 260 °C drop, CaSX 300 °C drop) approach their limits.

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